E-ISSN 0976-2779 | ISSN 0975-8453
 

Review Article 


Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher.

Abstract
The research involves synthesizing and characterizing a new ligand )potassium 5-cyano-3-formyl-1H-indole-1-carbodithioate( containing two atoms of the sulfur donor. The ligand was synthesized for 4 hours in the presence of alkali base (NaOH) through the reaction of one derivative of carbon disulfide and 3-Formyl-1H-indole5-carbonitrile in ethanol (as a solvent). Dithiocarbamate ligand was characterized along with the melting point using FT-IR, 1H NMR,13C-NMR, elemental analysis (C.H.N.S), UV-visible, and ESI-mass spectrum. Four metal complexes are prepared under refluxing. The complexes were prepared for 4 hours from the reaction of 2 potassium dithiocarbamate equivalent ligand with 1equivalent metal salt in refluxing ethanol. For other complexes the complexes were characterized by FT-IR, UV-Visible, molar conductivity, magnetic sensitivity measurements, flammable atomic absorption spectroscopy solubility, melting point, product microanalysis and mass spectroscopy. The biological function of the synthesized dithiocarbamate ligand and its complexes has been examined using inhibition method for two types of bacteria; one gram positive and one gram negative, and one type of pathogenic fungus. This will assess their possible antimicrobial activity.

Key words: potassium 5-cyano-3-formyl-1h-indole-1-carbodithioate, metal complexes, synthesis


 
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Pubmed Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. SRP. 2020; 11(6): 360-368. doi:10.31838/srp.2020.6.57


Web Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. http://www.sysrevpharm.org//?mno=116262 [Access: June 18, 2020]. doi:10.31838/srp.2020.6.57


AMA (American Medical Association) Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. SRP. 2020; 11(6): 360-368. doi:10.31838/srp.2020.6.57



Vancouver/ICMJE Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. SRP. (2020), [cited June 18, 2020]; 11(6): 360-368. doi:10.31838/srp.2020.6.57



Harvard Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher (2020) Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. SRP, 11 (6), 360-368. doi:10.31838/srp.2020.6.57



Turabian Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. 2020. Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. Systematic Reviews in Pharmacy, 11 (6), 360-368. doi:10.31838/srp.2020.6.57



Chicago Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. "Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity." Systematic Reviews in Pharmacy 11 (2020), 360-368. doi:10.31838/srp.2020.6.57



MLA (The Modern Language Association) Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher. "Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity." Systematic Reviews in Pharmacy 11.6 (2020), 360-368. Print. doi:10.31838/srp.2020.6.57



APA (American Psychological Association) Style

Ghufran Sh. Al-Obaidy, Kaiss R. Ibraheem, Mohammad F.Mesher (2020) Metal Complexes Derived from Dithiocarbamate Ligand: Formation, Spectral Characterization and Biological activity. Systematic Reviews in Pharmacy, 11 (6), 360-368. doi:10.31838/srp.2020.6.57





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